昭和51年2月19日
平成6年3月 秋田県立大館鳳鳴高等学校卒業
平成10年3月 東北大学理学部化学科卒業
平成15年3月 東北大学大学院理学研究科化学専攻博士課程後期課程修了
(指導教官 吉良 満夫教授)、博士(理学)取得
平成12年4月~平成15年3月 日本学術振興会特別研究員(DC1)
平成15年4月~平成18年3月 日本学術振興会特別研究員(PD)
京都大学化学研究所、小松 紘一教授
平成18年4月~平成18年9月 東北大学大学院理学研究科化学専攻 博士研究員
平成18年10月~平成19年3月 群馬大学大学院工学研究科ナノ材料システム工学専攻 助手
平成19年4月~平成21年6月 群馬大学大学院工学研究科応用化学・生物化学専攻 助教
(改組および呼称変更による)
平成21年7月~ 東北大学大学院理学研究科化学専攻 講師
平成28年2月~ 東北大学大学院理学研究科化学専攻 准教授
平成11年11月 第4回ケイ素化学協会シンポジウムポスター賞
平成14年11月 第7回ケイ素化学協会シンポジウムポスター賞
平成15年3月 日本化学会第83春期年会学生講演賞
平成15年3月 平成14年度東北大学総長賞
平成16年2月 第20回井上研究奨励賞「初めての安定なジアルキルシリレンおよびトリシラアレンの合成、構造および反応」
平成24年10月 第17回ケイ素化学協会奨励賞「安定シリレンの特徴的な反応を利用した新規含ケイ素π電子系の創製」
平成26年12月 有機合成化学奨励賞「二配位高周期15族ラジカルの速度論的安定化および関連化合物の化学」
Transformation of a Tetrasila-1,3-dienide to Its Valence Isomers
A Stable π-Expanded o-Quinodimethane via the Photochemical Dearomative Cycloaddition of Corannulene with an Isolable Dialkylsilylene
Synthesis of a dilithiobutadiene bearing extremely bulky silyl substituents and its reactivity toward functionalized silanes
Sulfur and Oxygen Transfer Reactions with Simultaneous NHC-Coordination from Cyclic Thioureas and Ureas to a Stable Silylene
Isolable Si=B Analogue of a Vinyl Halide: A Building Block for Facile Access toward Silicon-Boron Multiple Bonded Species
Metal-catalyzed valence isomerization of a methylene(thioxo)phosphorane to a thiaphosphirane
Selective Synthesis of New Hexaalkylbicyclo[1.1.1]pentasilanes with Improved Solubility
An Isolable THF-coordinated Dialkylgermanone
Synthesis of Phosphinoboranes via Coordination-Induced Bromine Abstraction of an Isolable Phosphinyl Radical with Bromoboranes
Coordination-Induced Migration of Aryl Groups in the Reactions of a Dialkylsilanone with a Series of Triarylboranes
Silacyclopropenylsilylene-NHC Complex: Synthesis by (1+2) Retro-cycloaddition, Dynamic Behavior in Solution, and Ring-expansion Reaction
Dearomative Cycloaddition of an Isolable Dialkylsilylene with Diaryl Ketones
Silyl(Silylene) Coinage Metal Complexes Obtained from Isolable Cyclic Alkylsilylenes
Synthesis, Structure and Electronic Properties of a Stable π-Type 3-Electron-2-Center-Bonded Species: A Silicon Analogue of a Bicyclo[1.1.0]butane Radical Anion
A Thermally Robust Cyclic Dialkylsilylene
Skeletal isomerism within 1,3-disilabicyclo[1.1.0]butane and 2,3-disilabuta-1,3-diene derivatives
Lithiated 1,3-Disilabicyclo[1.1.0]butanes via Selective Cleavage of Exocyclic Si-Si Bonds on Bridgehead Silicon Atoms
Synthesis of an NHC-Coordinated Dialkyldisilavinylidene and its Oxidation Providing a Silicon Analog of an Acetolactone
Dialkylboryl-Substituted Cyclic Disilenes Synthesized by Desilylation-Borylation of Trimethylsilyl-Substituted Disilenes
A Spiropentasiladiene Radical Cation: Spin and Positive Charge Delocalization across Two Perpendicular Si=Si Bonds and UV-vis-NIR Absorption in the IR-B Region
An Isolable Bromosilene: Synthesis, Structure, and Substitution Reactions
Cleavage of C-O and C-H bonds in ethers by a genuine Si=O bond
Naphtho- and anthra-disilacyclobutadienes
A Six-coordinate Silicon Dihydride Embedded in a Porphyrin: Enhanced Hydride-donor Properties and the Catalyst-free Hydrosilylation of CO2
Trialkylphosphines Having a Bulky Phosphacyclopentane Backbone: Structural and Redox Properties Depending on the Exocyclic Alkyl Groups and EPR Observation of a Persistent Trialkylphosphine Radical Cation
[1+2] Cycloaddition of a Cyclic (Alkyl)(amino)silylene and a Disilyne Providing a 3-Aminocyclotrisilene
Structures and Properties of Phenylene-bridged 1,3-Diaza-2-silole and Related 2H-Azasilirenes Obtained by the Reactions of a Dialkylsilylene with Arylnitriles
An Isolable Silicon Analogue of a Ketone that Contains an Unperturbed Si=O Double Bond
Reactions of a tetrasilabicyclo[1.1.0]but-1(3)-ene with carbon tetrachloride and methanol
Virtual Reaction Condition Optimization based on Machine Learning for a Small Number of Experiments in High-dimensional Continuous and Discrete Variables
A Tetrasilicon Analogue of Bicyclo[1.1.0]but-1(3)-ene Containing a Si=Si Double Bond with an Inverted Geometry
Transformative Si8R8 Siliconoids
Alkoxy(tetraaryl)silicates bearing 9,10-disilatriptycene skeleton
Dearomative Cycloadditions of a Silylene with Pyrazine and Quinoxaline
Facile Skeletal Rearrangement of Polycyclic Disilenes with Bicyclo[1.1.1]pentasilanyl Groups
A Series of Two-coordinate Group-15 Element (P, As, Sb, Bi) Centered Radicals Having Bulky Alkyl Groups
Synthesis and Functionalization of a 1,2-Bis(trimethylsilyl)-1,2-disilacyclohexene That Can Serve as a Unit of cis-1,2-Dialkyldisilene
Structural Change upon One-Electron Reduction of an Isolable Dialkylsilylene
Facile synthesis and bridgehead-functionalization of bicyclo[3.3.3]pentasiloxanes
Benzodisilacyclobutadienes: 8π-Electron Systems with An Antiaromatic Silicon Ring
Heteroaryldisilenes: heteroaryl groups serve as electron acceptors for Si=Si double bonds in the intramolecular charge transfer transitions
A 1,2-Dibromosilene: Generation, Spectroscopic Observation and Isomerization to a Silacyclohexane via Facile 1,2-Bromine Shift
Coordination-induced Hydrogen Abstraction in the Reactions of a Stable Dialkylphosphinyl Radical with BH3-Lewis Base Adducts
Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene
Pentasila-1,4-diene: Homoconjugation between Si=Si Double Bonds via a SiMe2 Unit
A Two-Coordinate Cyclic (Alkyl)(amino)silylene: Balancing Thermal Stability and Reactivity
A Potassium Diboryllithate: Synthesis, Bonding Properties, and the Deprotonation of Benzene
Hydrogen Bonds-Enabled Design of a C1-Symmetric Chiral Brønsted Acid Catalyst
Ferrocenyl-substituted Bicyclo[1.1.1]pentasilanes: Evaluation of Significant Interactions between Ferrocenyl Units and Rigid Silicon Cages
Persistent four-coordinate iron-centered radical stabilized by π-donation
Recent Advances in η2-Disilene and η2-Disilyne Mononuclear Transition Metal Complexes and Related Compounds (For a special issue: Recent Developments in Organometallic Chemistry: 2016)
Persistent Dialkylsilanone Generated by Dehydrobromination of Dialkylbromosilanol
Transformation of azulenes to bicyclic [4]dendralene and heptafulvene derivatives by photochemical cycloaddition of dialkylsilylene
Redox Reactions of a Stable Dialkylphosphinyl Radical
Reactions of a Stable Phosphinyl Radical with Stable Aminoxyl Radicals
A heavy analogue of the smallest bridgehead alkene stabilized by a base
Two-coordinate Dialkylsilylene-Coinage Metal Complexes
Persistent Antimony- and Bismuth-Centered Radicals in Solution
Germanium-centered free radicals studied by muon spin spectroscopy
Isolable 2,3-Disila-1,3-butadiene via Double Sila-Peterson Reaction
Unexpected Formation of Highly Strained 2,5-Dioxa-Silabicyclo[2.1.0]Pentane by the Reaction of Isolable Dialkylsilylene with Benzil
Silicon Compounds with Inverted Geometry around Silicon Atoms
Multiple Bonds with Silicon: Recent Advances in Synthesis, Structure, and Functions of Stable Disilenes
Palladium and Platinum η2-Disilyne Complexes Bearing an Isolable Dialkyldisilyne as a Ligand
Anthryl-substituted 3-Silylene-2-silaaziridine Obtained by Isomerization of Disilacyclopropanimine: An Exocyclic Silene Showing Distinct Intramolecular Charge Transfer Transition
Microwave-Assisted Efficient One-Pot Synthesis of 9-Phenyl-9,10-disilatriptycene and Its Bridgehead Functionalization
An Organosilicon Cluster with an Octasilacuneane Core: A Missing Silicon Cage Motif
New Isolable Dialkylsilylene and Its Isolable Dimer That Equilibrate in Solution
A Two-Coordinate Palladium Complex with Two Dialkylphosphinyl Ligands
Siloxy-Substituted Cyclopentadiene Showing Aggregation-Enhanced Emission: An Application of Cycloaddition of Isolable Dialkylsilylene
Persilastaffanes: Design, Synthesis, Structure, and Conjugation between Silicon Cages
A Stable Dialkylphosphinyl Radical
Addition of a Stable Dialkylsilylene to Carbon-carbon Unsaturated Bonds
Synthesis and properties of 5,10,15,20-tetrakis[4-(alkoxysilyl)phenyl]porphyrins: an application of selective deprotection of benzaldehyde diethyl acetals in the presence of alkoxysilyl groups
Reactions of an Isolable Dialkylsilylene with Ketones
Selective Si-C Bond Cleavage on a Diorganosilicon Porphyrin Complex Bearing Different Axial Ligands
Isomerization of an Isolable Silylene into a Silene via 1,2-Silyl Migration
Generation and Aromaticity of 2-Silaimidazolium Ion, a New p-Conjugated Silylium Ion
The First Isolation of 1,3-Diaza-2-Sila-4-Cyclopentene Radical Cation Salt: The X-ray Structure and Electronic Properties
A Stable Silicon-based Allene Analogue with a Formally sp-Hybridized Silicon Atom
The First Isolable Dialkylsilylene
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